Rare Earth Elements
Monazite
is a rare phosphate mineral with a
chemical composition of (Ce,La,Nd,Th)(PO4,SiO4). It usually occurs in small
isolated grains, as an accessory mineral in igneous and metamorphic rocks
such as granite, pegmatite, schist, and gneiss. These grains are
resistant to weathering and become concentrated in soils and sediments downslope
from the host rock. When in high enough concentrations, they are mined for
their rare earth
and thorium content.
Monazite Mineral
Group
|
|
Mineral
|
Chemical Composition
|
Brabantite
|
CaTh(PO4)2
|
Cheralite
|
(Ca,Ce,Th)(P,Si)O4
|
Gasparite-(Ce)
|
(Ce,La,Nd)AsO4
|
Monazite-(Ce)
|
CePO4
|
Monazite-(La)
|
LaPO4
|
Monazite-(Nd)
|
NdPO4
|
Monazite-(Sm)
|
SmPO4
|
Rooseveltite
|
BiAsO4
|
Monazite is a yellowish
brown to reddish brown or greenish brown mineral with a resinous to vitreous
luster
Monazite
is known more for where it accumulates instead of where it forms. It forms
during the crystallization of igneous rocks and during the metamorphism of
clastic sedimentary
rocks. When these rocks weather, monazite is one of the more
resistant minerals and becomes concentrated in the weathering debris. The soils
and sediments found near a weathering outcrop can have a higher concentration
of monazite than the source rock.The liberated grains of monazite then begin a journey downslope. Eventually they are brought to a stream or a dry wash. There, the actions of gravity and running water help the heavy grains of monazite and other heavy minerals segregate from lighter minerals. They accumulate behind boulders, on the inside bends of stream channels and work their way down into the lower portions of the sediment deposit. Some are washed to the sea where they accumulate in deltaic, beach, or shallow water sediments.
Today,
most of the world's monazite is produced in the offshore waters of India,
Malaysia, Vietnam, and Brazil. Southern India and Sri Lanka have the most
extensive offshore monazite resources known. Australia was once the world's
largest producer of monazite and is thought to have the world's largest
monazite resource. It has not been a significant producer since the 1990s,
after public objection shut down mining on Frasier IslandRare earth elements
play an essential role in our national defense. The military uses night-vision
goggles, precision-guided weapons, communications equipment, GPS equipment,
batteries, and other defense electronics. These give the United States military
an enormous advantage. Rare earth metals are key ingredients for making the
very hard alloys used in armored vehicles and projectiles that shatter upon
impact.
Before
1965 there was relatively little demand for rare earth elements. At that time,
most of the world's supply was being produced from placer deposits in India and
Brazil. In the 1950s, South Africa became the leading producer from rare earth
bearing monazite
deposits. At that time, the Mountain Pass Mine in California was producing
minor amounts of rare earth oxides from a Precambrian carbonatite.
The
demand for rare earth elements saw its first explosion in the mid-1960s, as the
first color television sets were entering the market. Europium was the
essential material for producing the color images. The Mountain Pass Mine began
producing europium from bastnasite, which contained about 0.1% europium. This
effort made the Mountain Pass Mine the largest rare earth producer in the world
and placed the United States as the leading producer.
"Rare
earths are relatively abundant in the Earth's crust, but discovered minable
concentrations are less common than for most other ores. U.S. and world
resources are contained primarily in bastnäsite and monazite. Bastnäsite
deposits in China and the United States constitute the largest percentage of
the world's rare-earth economic resources, while monazite deposits in Australia,
Brazil, China, India, Malaysia, South Africa, Sri Lanka, Thailand, and the
United States constitute the second largest segment.
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