Friday 20 October 2017


Modern chemistry


A decisive moment came when 'chemistry' was distinguished from alchemy by Robert Boyle in his work The Sceptical Chymist, in 1661.Other important steps included the gravimetric experimental practices of medical chemists like William CullenJoseph BlackTorbern Bergman and Pierre Macquer and through the work of Antoine Lavoisier(Father of Modern Chemistry) on oxygen and the law of conservation of mass, which refuted phlogiston theory. The theory that all matter is made of atoms, which are the smallest constituents of matter that cannot be broken down without losing the basic chemical and physical properties of that matter, was provided by John Dalton in 1803. In 1869, Dmitri Mendeleev composed his periodic table of elements on the basis of Dalton's discoveries.
The synthesis of urea by Friedrich Wöhler opened a new research field, organic chemistry, and by the end of the 19th century, scientists were able to synthesize hundreds of organic compound. The 20th century also saw the integration of physics and chemistry, with chemical properties explained as the result of the electronic structure of the atom. Linus Pauling's book on The Nature of the Chemical Bond used the principles of quantum mechanics to deduce bond angles in ever-more complicated Pauling's work culminated in the physical modelling of DNAthe secret of life.
Midway through the 19th century, the focus of geology shifted from description and classification to attempts to understand how the surface of the Earth had changed. Geologists' embrace of plate tectonics became part of a broadening of the field from a study of rocks into a study of the Earth as a planet.
Antoine-Laurent de Lavoisier  was a French nobleman and chemist who was central to the 18th-century chemical revolution and who had a large influence on both the history of chemistry and the history of biology. He is widely considered in popular literature as the "father of modern chemistry".
It is generally accepted that Lavoisier's great accomplishments in chemistry largely stem from his changing the science from a qualitative to a quantitative one. Lavoisier is most noted for his discovery of the role oxygen plays in combustion. He recognized and named oxygen (1778) and hydrogen (1783) and opposed the phlogiston theory. Lavoisier helped construct the metric system, wrote the first extensive list of elements, and helped to reform chemical nomenclature. He predicted the existence of silicon (1787) and was also the first to establish that sulfur was an element (1777) rather than a compound. He discovered that, although matter may change its form or shape, its mass always remains the same.

Oxygen theory of combustion
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During late 1772 Lavoisier turned his attention to the phenomenon of combustion, the topic on which he was to make his most significant contribution to science. He reported the results of his first experiments on combustion in a note to the Academy on 20 October, in which he reported that when phosphorus burned, it combined with a large quantity of air to produce acid spirit of phosphorus, and that the phosphorus increased in weight on burning. In a second sealed note deposited with the Academy a few weeks later (1 November) Lavoisier extended his observations and conclusions to the burning of sulfur and went on to add that "what is observed in the combustion of sulfur and phosphorus may well take place in the case of all substances that gain in weight by combustion and calcination: and I am persuaded that the increase in weight of metallic calces is due to the same cause."

Joseph Black's "fixed air"

During 1773 Lavoisier determined to review thoroughly the literature on air, particularly "fixed air," and to repeat many of the experiments of other workers in the field. He published an account of this review in 1774 in a book entitled Physical and Chemical Essays. In the course of this review he made his first full study of the work of Joseph Black, the Scottish chemist who had carried out a series of classic quantitative experiments on the mild and caustic alkalies. Black had shown that the difference between a mild alkali, for example, chalk (CaCO3), and the caustic form, for example, quicklime (CaO), lay in the fact that the former contained "fixed air," not common air fixed in the chalk, but a distinct chemical species, now understood to be carbon dioxide (CO2), which was a constituent of the atmosphere. Lavoisier recognized that Black's fixed air was identical with the air evolved when metal calces were reduced with the charcoal and even suggested that the air which combined with metals on calcination and increased the weight might be Black's fixed air, that is, CO2.

Joseph Priestley


Joseph Priestley, an English chemist known for isolating oxygen, which he termed "dephlogisticated air."
In the spring of 1774 Lavoisier carried out experiments on the calcination of tin and lead in sealed vessels which conclusively confirmed that the increase in weight of metals in combustion was due to combination with air. But the question remained about whether it was combination with common atmospheric air or with only a part of atmospheric air. In October the English chemist Joseph Priestley visited Paris, where he met Lavoisier and told him of the air which he had produced by heating the red calx of mercury with a burning glass and which had supported combustion with extreme vigor. Priestley at this time was unsure of the nature of this gas, but he felt that it was an especially pure form of common air. Lavoisier carried out his own researches on this peculiar substance. The result was his famous memoir On the Nature of the Principle Which Combines with Metals during Their Calcination and Increases Their Weight, read to the Academy on 26 April 1775. In the original memoir Lavoisier showed that the mercury calx was a true metallic calx in that it could be reduced with charcoal, giving off Black's fixed air in the process. When reduced without charcoal, it gave off an air which supported respiration and combustion in an enhanced way. He concluded that this was just a pure form of common air, and that it was the air itself "undivided, without alteration, without decomposition" which combined with metals on calcination.
After returning from Paris, Priestley took up once again his investigation of the air from mercury calx. His results now showed that this air was not just an especially pure form of common air but was "five or six times better than common air, for the purpose of respiration, inflammation, and ... every other use of common air." He called the air dephlogisticated air, as he thought it was common air deprived of its phlogiston. Since it was therefore in a state to absorb a much greater quantity of phlogiston given off by burning bodies and respiring animals, the greatly enhanced combustion of substances and the greater ease of breathing in this air were explained

Pioneer of stoichiometry

Lavoisier's researches included some of the first truly quantitative chemical experiments. He carefully weighed the reactants and products of a chemical reaction in a sealed glass vessel so that no gases could escape, which was a crucial step in the advancement of chemistry.In 1774, he showed that, although matter can change its state in a chemical reaction, the total mass of matter is the same at the end as at the beginning of every chemical change. Thus, for instance, if a piece of wood is burned to ashes, the total mass remains unchanged if gaseous reactants and products are included. Lavoisier's experiments supported the law of conservation of mass. In France it is taught as Lavoisier's Law and is paraphrased from a statement in his "Nothing is lost, nothing is created, everything is transformed. Mikhail Lomonosov (1711–1765) had previously expressed similar ideas in 1748 and proved them in experiments; others whose ideas pre-date the work of Lavoisier include Jean Rey (1583–1645), Joseph Black (1728–1799), and Henry Cavendish (1731–1810).

Modern Chemistry (20th Century Chemistry) - Mid 19th Century to Present; This is the era chemistry flourished. Lavoisier's thesis gave chemists the first sound understanding of the nature of chemical reactions. Lavoisier's work led an English school teacher by the name of John Dalton to formulate his atomic theory. Around the same time an Italian chemist, Amedeo Avogadro formulated his own theory (Avogadro's Law) concerning molecules and their relation to temperature and pressure.  By the middle of the 19th century, there were approximately 60 known elements. John A.R. Newlands, Stanislao Cannizzaro and A.E.B. de Chancourtois first noticed that all of these elements were very much alike in structure. Their work led Dmitri Mendeleev to publish the first periodic table.  Mendeleev's work set the foundation of theoretical chemistry. In 1896 Henri Becquerel and the Curies discovered the phenomenon known as radioactivity. This laid the foundation for nuclear chemistry. In 1919, Ernest Rutherford became discovered that elements could be transmutated. Rutherford's work laid the basis for interpreting the structure of the atom. Soon after, another chemist, Niels Bohr finalized the atomic theory. These and other major advanced in chemistry have led to many distinct branches of chemistry. These branches include, but are not limited to: biochemistry, nuclear chemistry, chemical engineering, organic chemistry.

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