Modern chemistry
The synthesis
of urea by Friedrich
Wöhler opened a new
research field, organic chemistry, and by the end of the 19th century,
scientists were able to synthesize hundreds of organic compound. The 20th
century also saw the integration of physics and chemistry, with chemical
properties explained as the result of the electronic structure of the
atom. Linus
Pauling's book on The
Nature of the Chemical Bond used the principles of quantum mechanics
to deduce bond angles in ever-more complicated Pauling's work
culminated in the physical modelling of DNA, the
secret of life.
Midway through the
19th century, the focus of geology shifted from description and classification
to attempts to understand how the surface of the Earth had
changed. Geologists' embrace of plate tectonics became part of a broadening of the field
from a study of rocks into a study of the Earth as a planet.
Antoine-Laurent de Lavoisier
was a
French nobleman and
chemist
who was central to the 18th-century
chemical revolution and who
had a large influence on both the
history of chemistry and the
history of biology. He is widely
considered in popular literature as the "
father
of modern chemistry".
It is generally accepted that Lavoisier's great accomplishments in chemistry
largely stem from his changing the science from a qualitative to a quantitative
one. Lavoisier is most noted for his discovery of the role
oxygen
plays in
combustion.
He recognized and named
oxygen (1778) and
hydrogen
(1783) and opposed the
phlogiston theory. Lavoisier
helped construct the
metric system, wrote the first
extensive
list of elements,
and helped to reform
chemical nomenclature. He
predicted the existence of
silicon (1787) and was also
the first to establish that
sulfur was an element (1777) rather than a compound.
He discovered that, although matter may change its form or shape,
its mass always remains the same.
Oxygen
theory of combustion
.
During late 1772 Lavoisier turned
his attention to the phenomenon of combustion,
the topic on which he was to make his most significant contribution to science.
He reported the results of his first experiments on combustion in a note to the
Academy on 20 October, in which he reported that when phosphorus
burned, it combined with a large quantity of air to produce acid spirit of phosphorus,
and that the phosphorus increased in weight on burning. In a second sealed note
deposited with the Academy a few weeks later (1 November) Lavoisier extended
his observations and conclusions to the burning of sulfur and went
on to add that "what is observed in the combustion of sulfur and
phosphorus may well take place in the case of all substances that gain in
weight by combustion and calcination: and I am persuaded that the increase in
weight of metallic calces is due to the same cause."
Joseph Black's "fixed air"
During 1773 Lavoisier determined to review thoroughly the literature on air,
particularly "fixed air," and to repeat many of the experiments of
other workers in the field. He published an account of this review in 1774 in a
book entitled Physical and Chemical Essays. In the course of this review he
made his first full study of the work of
Joseph
Black, the Scottish chemist who had carried out a series of classic
quantitative experiments on the mild and caustic alkalies. Black had shown that
the difference between a mild alkali, for example,
chalk (
CaCO3), and the caustic form, for example,
quicklime
(
CaO),
lay in the fact that the former contained "fixed air," not common air
fixed in the chalk, but a distinct chemical species, now understood to be
carbon
dioxide (CO
2), which
was a constituent of the atmosphere. Lavoisier recognized that Black's fixed
air was identical with the air evolved when metal calces were reduced with the
charcoal and even suggested that the air which combined with metals on
calcination and increased the weight might be Black's fixed air, that is, CO
2.
Joseph Priestley
In the spring of 1774 Lavoisier carried out experiments on the calcination
of tin and lead in sealed vessels which conclusively confirmed that the
increase in weight of metals in combustion was due to combination with air. But
the question remained about whether it was combination with common atmospheric
air or with only a part of atmospheric air. In October the English chemist
Joseph
Priestley visited Paris, where he met Lavoisier and told him of the
air which he had produced by heating the
red
calx of mercury with a burning glass and which had supported
combustion with extreme vigor. Priestley at this time was unsure of the nature
of this gas, but he felt that it was an especially pure form of common air.
Lavoisier carried out his own researches on this peculiar substance. The result
was his famous memoir
On the Nature of the Principle Which Combines with
Metals during Their Calcination and Increases Their Weight, read to the Academy
on 26 April 1775. In the original memoir Lavoisier showed that the mercury calx
was a true metallic calx in that it could be reduced with
charcoal,
giving off Black's fixed air in the process. When reduced without charcoal, it
gave off an air which supported respiration and combustion in an enhanced way.
He concluded that this was just a pure form of common air, and that it was the
air itself "undivided, without alteration, without decomposition"
which combined with metals on calcination.
After returning from Paris, Priestley took up once again his investigation
of the air from mercury calx. His results now showed that this air was not just
an especially pure form of common air but was "five or six times better
than common air, for the purpose of respiration, inflammation, and ... every
other use of common air." He called the air dephlogisticated air, as he
thought it was common air deprived of its phlogiston. Since it was therefore in
a state to absorb a much greater quantity of phlogiston given off by burning
bodies and respiring animals, the greatly enhanced combustion of substances and
the greater ease of breathing in this air were explained
Pioneer of stoichiometry
Lavoisier's researches included some of the first truly
quantitative
chemical experiments. He carefully weighed the reactants and
products of a chemical reaction in a sealed glass vessel so that no
gases could
escape, which was a crucial step in the advancement of chemistry.In 1774, he
showed that, although matter can change its state in a chemical reaction, the
total mass of matter is the same at the end as at the beginning of every
chemical change. Thus, for instance, if a piece of wood is burned to ashes, the
total mass remains unchanged if gaseous reactants and products are included.
Lavoisier's experiments supported the law of
conservation of mass. In
France it is taught as Lavoisier's Law and is paraphrased from a statement in
his
"Nothing is lost, nothing is created, everything is transformed.
Mikhail Lomonosov (1711–1765)
had previously expressed similar ideas in 1748 and proved them in experiments;
others whose ideas pre-date the work of Lavoisier include
Jean Rey (1583–1645),
Joseph
Black (1728–1799), and
Henry
Cavendish (1731–1810).
Modern Chemistry (20th Century Chemistry) - Mid 19th Century to Present;
This is the era chemistry flourished. Lavoisier's thesis gave chemists the
first sound understanding of the nature of chemical reactions. Lavoisier's work
led an English school teacher by the name of John Dalton to formulate his
atomic theory. Around the same time an Italian chemist, Amedeo Avogadro
formulated his own theory (Avogadro's Law) concerning molecules and their
relation to temperature and pressure. By
the middle of the 19th century, there were approximately 60 known elements.
John A.R. Newlands, Stanislao Cannizzaro and A.E.B. de Chancourtois first
noticed that all of these elements were very much alike in structure. Their
work led Dmitri Mendeleev to publish the first periodic table. Mendeleev's work set the foundation of
theoretical chemistry. In 1896 Henri Becquerel and the Curies discovered the
phenomenon known as radioactivity. This laid the foundation for nuclear
chemistry. In 1919, Ernest Rutherford became discovered that elements could be
transmutated. Rutherford's work laid the basis for interpreting the structure
of the atom. Soon after, another chemist, Niels Bohr finalized the atomic
theory. These and other major advanced in chemistry have led to many distinct
branches of chemistry. These branches include, but are not limited to: biochemistry,
nuclear chemistry, chemical engineering, organic chemistry.